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Published online 1 May 2008
Published in J Environ Qual 37:817-823 (2008)
DOI: 10.2134/jeq2007.0217
© 2008 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
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Sorption of Aromatic Compounds to Clay Mineral and Model Humic Substance–Clay Complex: Effects of Solute Structure and Exchangeable Cation

Yingjie Zhang, Dongqiang Zhu* and Hongxia Yu

State Key Lab. of Pollution Control and Resource Reuse, and School of the Environment, Nanjing Univ., Jiangsu 210093, P.R. China


Figure 1
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Fig. 1. Chemical structures of sorbates.

 

Figure 2
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Fig. 2. Sorption isotherms for all compounds. (a) Original for K+–clay and humic substance (HS)–K+–clay. (b) Normalized for hydrophobic effect using solute aqueous solubility (SW) for K+–clay. CBL, carbaryl; DNB, 1,3-dinitrobenzene; DNL, dichlobenil; PHEN, phenanthrene; TeCB, 1,2,4,5-tetrachlorobenzene.

 

Figure 3
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Fig. 3. Sorption isotherms for phenanthrene to clays and humic substance (HS)–clay complexes saturated with different cations of Na+, K+, Cs+, and Ca2+.

 

Figure 4
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Fig. 4. Sorption isotherms for 1,3-dinitrobenzene to clays and humic substance (HS)–clay complexes saturated with different cations of Na+, K+, Cs+, and Ca2+.

 

Figure 5
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Fig. 5. Sorption isotherms for all compounds to humic substances. (a) Original. (b) Normalized for hydrophobic effect using solute aqueous solubility (SW). CBL, carbaryl; DNB, 1,3-dinitrobenzene; DNL, dichlobenil; PHEN, phenanthrene; TeCB, 1,2,4,5-tetrachlorobenzene.

 





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