Published online 1 May 2008
Published in J Environ Qual 37:1064-1072 (2008)
DOI: 10.2134/jeq2006.0562
© 2008 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
Simulated Fate and Transport of Metolachlor in the Unsaturated Zone, Maryland, USA
E. Randall Baylessa,*,
Paul D. Capelb,
Jack E. Barbashc,
Richard M. T. Webbd,
Tracy L. Connell Hancocke and
David C. Lampef
a USGS, 5957 Lakeside Blvd., Indianapolis, IN 46278
b USGS, 500 Pillsbury Dr., Minneapolis, MN 22807
c USGS, 934 Broadway, Tacoma, WA 98402
d USGS, MS 412, Denver Federal Center, Denver, CO 80225-0046
e USGS, 1730 East Parham Rd., Richmond, VA 23228
f USGS, 5957 Lakeside Blvd., Indianapolis, IN 46278. Commercial names are provided for purposes of identification only and should not be interpreted as an endorsement by the U.S. Geological Survey

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Fig. 1. Measured and simulated bromide concentrations at 0.5 m depth. Squares indicate measured bromide concentrations; triangles indicate bromide concentrations less than the minimum reporting limit.
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Fig. 3. Simulated and measured (A) metolachlor ethanesulfonic acid (MESA) and (B) metolachlor oxanilic acid (MOXA) concentrations at 0.5 m. Diamonds indicate measured degradate concentrations.
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Fig. 4. Simulated distribution of aqueous and sorbed concentrations of (A) metolachlor, (B) metolachlor ethanesulfonic acid (MESA), and (C) metolachlor oxanilic acid (MOXA) in the unsaturated zone. Units of adsorbed species are µg g–1; aqueous species are mg L–1.
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Fig. 5. Plot of (A) metolachlor after 3, 5, 10, 15, and 20 yr of biannual metolachlor applications, (B) metolachlor ethanesulfonic acid (MESA) with aerobic-soil zone (only) degradation, and (C) MESA with uniform soil-profile degradation.
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Copyright © 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.