Published online 24 October 2007
Published in J Environ Qual 36:1784-1792 (2007)
DOI: 10.2134/jeq2007.0143
© 2007 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
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The Leaching Characteristics of Selenium from Coal Fly Ashes
Tian Wanga,
Jianmin Wanga,*,*,
Joel G. Burken1,
Heng Ban2 and
Ken Ladwig3
a Dep. of Civil, Architectural & Environmental Engineering, Univ. of Missouri, Rolla, MO 65409
b Dep. of Mechanical & Aerospace Engineering, Utah State Univ., Logan, UT 84322
c Electric Power Research Inst. (EPRI), 3420 Hillview Ave., Palo Alto, CA 94304

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Fig. 1. Selenium leaching from bituminous and subbituminous coal fly ashes. Experimental conditions: S/L = 1:10; temperature = 20–25°C; equilibration time = 24 h.
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Fig. 2. Soluble selenium concentrations as a function of pH under different selenium addition conditions for 0.2 mol/L NaOH washed ash #1004: (a) Se(VI) and (b) Se(IV). Experimental conditions: S/L = 1:10; ionic strength = 0.01 mol/L NaNO3; temperature = 20–25°C; equilibration time = 24 h.
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Fig. 3. Selenium adsorption results in single and mixed species systems for different types of ashes: (a) 0.2 mol/L NaOH washed bituminous coal ash # 1009; and (b) DI water washed subbituminous coal ash #1018. Experimental conditions were same as Fig. 2.
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Fig. 4. Sulfate impact on selenium adsorption for different types of ashes: (a) 0.2 mol/L NaOH washed bituminous coal ash # 1009; and (b) DI water washed subbituminous coal ash #1018. Experimental conditions were same as Fig. 2.
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Fig. 5. Titration and curve fitting results for (a) 0.2 mol/L NaOH washed ash #1004 and (b) DI water washed ash #1008. Experimental conditions: S/L = 1:10; ionic strength = 0.01 mol/L (NaNO3); temperature = 20–25°C; equilibration time = 24 h.
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Fig. 6. Se(IV) partitioning results–experimental data and modeling result for (a) 0.2 mol/L NaOH washed ash #1004 and (b) DI water washed ash #1008. Experimental conditions were same as Fig. 2.
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Copyright © 2007 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.