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Published online 9 August 2006
Published in J Environ Qual 35:1702-1714 (2006)
DOI: 10.2134/jeq2005.0412
© 2006 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
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Modeling the Environmental Fate of Cadmium in a Large Wastewater Irrigation Area

Joachim Ingwersen* and Thilo Streck

Univ. of Hohenheim, Institute of Soil Science and Land Evaluation, Biogeophysics Section, D-70593 Stuttgart, Germany


Figure 1
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Fig. 1. Sketch of the wastewater irrigation area (WIA) of Braunschweig, most important installations, and sampling sites.

 

Figure 2
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Fig. 2. Experimental and fitted semivariograms of (A) soil pH in 0.9 to 1.0 m layers (exponential model: sill = 0.365, range = 937 m), (B) organic carbon content in Ap horizons (spherical model: nugget = 0.053, partial sill = 0.154, range = 2192 m), and (C) Cd loads (exponential model: nugget = 0.145 mg2 m–2, partial sill = 0.219 mg2 m–2, range = 429 m). Organic carbon contents (% by mass) and Cd loads were log-transformed before analysis.
 

Figure 3
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Fig. 3. Histograms of soil pH in (A) Ap horizons and (B) 0.9–1.0 m layers. The curves are fitted normal distributions.

 

Figure 4
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Fig. 4. Reconstructed cadmium input to the districts of the wastewater irrigation area of Braunschweig.

 

Figure 5
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Fig. 5. Observed and simulated average Cd concentration profiles at non-Rigosol sites. (A) solution phase concentrations and (B) EDTA–extractable content.

 

Figure 6
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Fig. 6. Cadmium concentrations at non-Rigosol sites after up to 40 yr of wastewater irrigation. (A) All data and (B, C) two selected profiles.

 

Figure 7
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Fig. 7. Observed and simulated average Cd concentration profiles of Rigosols. (A) solution phase concentrations and (B) EDTA–extractable content.

 

Figure 8
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Fig. 8. Simulated regionally-averaged solution phase concentrations and EDTA–extractable Cd contents in 1996 and 2046. From 1996 to 2046, Cd load was kept at the level of 1996. Simulations were performed with the MC 2 approach.

 

Figure 9
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Fig. 9. Predicted average Cd concentrations in seepage water at the depth of water table. From 1996 to 2246, Cd load was kept at the level of 1996. Simulations were performed with the MC 2 approach.

 

Figure 10
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Fig. 10. Cadmium content in wheat grain for Scenario 2 and a hindcast simulation. Scenario 2 assumes that Cd loads were not reduced in the mid 1980s. In the hindcast simulation the reconstructed ("real") Cd input history was used.

 





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