Published online 31 May 2006
Published in J Environ Qual 35:1127-1134 (2006)
DOI: 10.2134/jeq2005.0136
© 2006 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
Sampling Silica and Ferrihydrite Colloids with Fiberglass Wicks under Unsaturated Conditions
Jason M. Shiraa,b,
Barbara C. Williamsc,*,
Markus Fluryd,
Szabolcs Czigányd,e and
Markus Tullerf
a Department of Environmental Science, University of Idaho, Moscow, ID 83844
b Current address: Washington State Department of Ecology, Olympia, WA 98504
c Department of Biological and Agricultural Engineering, University of Idaho, Moscow, ID 83844-0904
d Department of Crop and Soil Sciences, Center for Multiphase Environmental Research, Washington State University, Pullman, WA 99164
e Current address: Department of Physical Geography, Geographical Institute, University of Pécs, Hungary
f Soils and Land Resources Division, University of Idaho, Moscow, ID 83844-2339

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Fig. 1. Setup for unsaturated wick colloid transport experiments.
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Fig. 2. Scanning electron microscopy (SEM) image of fiberglass wick after cleaning process; notice impurity on one fiber after cleaning, which indicates that the cleaning process is not complete.
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Fig. 3. Liquid retention curve for fiberglass wick. Symbols are measured data, line is fitted van Genuchten relationship. Main hysteresis loop of retention curve is shown for drying limb only.
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Fig. 4. Vertical moisture profiles in fiberglass wick.
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Fig. 5. Breakthrough curves for nitrate and silica microspheres at different flow rates.
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Fig. 6. Breakthrough curves for ferrihydrite colloids at pH 4 (three replicates).
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Fig. 7. Conceptual depiction of fiberglass wick pore geometry; shading indicates degree of staining by ferrihydrite. Filament diameter measured with scanning electron microscopyenergy dispersive spectrometry (SEMEDS).
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Copyright © 2006 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.