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Published online 31 May 2006
Published in J Environ Qual 35:1127-1134 (2006)
DOI: 10.2134/jeq2005.0136
© 2006 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Sampling Silica and Ferrihydrite Colloids with Fiberglass Wicks under Unsaturated Conditions

Jason M. Shiraa,b, Barbara C. Williamsc,*, Markus Fluryd, Szabolcs Czigányd,e and Markus Tullerf

a Department of Environmental Science, University of Idaho, Moscow, ID 83844
b Current address: Washington State Department of Ecology, Olympia, WA 98504
c Department of Biological and Agricultural Engineering, University of Idaho, Moscow, ID 83844-0904
d Department of Crop and Soil Sciences, Center for Multiphase Environmental Research, Washington State University, Pullman, WA 99164
e Current address: Department of Physical Geography, Geographical Institute, University of Pécs, Hungary
f Soils and Land Resources Division, University of Idaho, Moscow, ID 83844-2339


Figure 1
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Fig. 1. Setup for unsaturated wick colloid transport experiments.

 

Figure 2
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Fig. 2. Scanning electron microscopy (SEM) image of fiberglass wick after cleaning process; notice impurity on one fiber after cleaning, which indicates that the cleaning process is not complete.

 

Figure 3
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Fig. 3. Liquid retention curve for fiberglass wick. Symbols are measured data, line is fitted van Genuchten relationship. Main hysteresis loop of retention curve is shown for drying limb only.

 

Figure 4
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Fig. 4. Vertical moisture profiles in fiberglass wick.

 

Figure 5
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Fig. 5. Breakthrough curves for nitrate and silica microspheres at different flow rates.

 

Figure 6
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Fig. 6. Breakthrough curves for ferrihydrite colloids at pH 4 (three replicates).

 

Figure 7
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Fig. 7. Conceptual depiction of fiberglass wick pore geometry; shading indicates degree of staining by ferrihydrite. Filament diameter measured with scanning electron microscopy–energy dispersive spectrometry (SEM–EDS).

 





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