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Published online 5 July 2005
Published in J Environ Qual 34:1380-1391 (2005)
DOI: 10.2134/jeq2004.0232
© 2005 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
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Establishing a Linkage between Phosphorus Forms in Dairy Diets, Feces, and Manures

Gurpal S. Toora,*, Barbara J. Cade-Menunb and J. Thomas Simsa

a Department of Plant and Soil Sciences, University of Delaware, Newark, DE 19716
b Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115



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Fig. 1. Relationship between total P concentrations in diets and feces of lactating cows. Open circles represents data from Dou et al. (2003) while black data points are from the present study.

 


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Fig. 2. Example 31P nuclear magnetic resonance (NMR) spectra of diets, feces, and manures from (a) low-P-diet farm and (b) high-P-diet farm. The main spectra are plotted to show orthophosphate at the same height, to give relative peak heights. Inset peaks show expanded regions of the main spectra.

 


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Fig. 3. Details showing the peaks for phytic acid in diet, feces, and manure samples, using samples collected from Farm C as an example. A spectrum for pure phytic acid, also extracted with NaOH-EDTA in the same manner as the farm samples, is shown on the bottom, with the P1, P2, P3, P4, and P6 peaks labeled. The areas under the same four peaks in the farm samples were determined both by manual plotting after integration and by spectral deconvolution. For the diet, feces, and manure samples, the solid line indicates the original spectrum, while the dotted lines show the phytic acid peaks as determined by spectral deconvolution. Other peaks determined by spectral deconvolution are not shown. Spectra are plotted with 1-Hz line-broadening.

 


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Fig. 4. Relationship between diet, feces, and manure total P with orthophosphate and phytic acid.

 





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Copyright © 2005 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.