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Right arrow Humic Substances
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Structural and Sorption Characteristics of Adsorbed Humic Acid on Clay Minerals

Kaijun Wang and Baoshan Xing*

Department of Plant, Soil and Insect Sciences, University of Massachusetts, Amherst, MA 01003



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Fig. 1. Carbon-13 nuclear magnetic resonance (NMR) spectra: (A) solid-state NMR spectra of montmorillonite–humic acid (HA) complex; (B) rotor background spectrum; (C) differential spectrum between A and B (i.e., difference of free induction decay signals); (D) liquid-state NMR spectrum of the HA left in the solution after coating on montmorillonite; (E) solid-state NMR spectra of the HA left in solution after coating on kaolinite and freeze-drying; and (F) solid-state NMR of the source HA.

 


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Fig. 2. Phenanthrene sorption isotherms: (A) the source humic acid (HA); (B) montmorillonite and montmorillonite–HA complex at a HA to clay ratio of 1 to 5; and (C) kaolinite and kaolinite–HA complex at a HA to clay ratio of 1 to 5. The inserted graphs in (B) and (C) are the isotherms in linear scale of (B) and (C), respectively.

 





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