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Long-Term Effects of Nitrogen Fertilizer Use on Ground Water Nitrate in Two Small Watersheds

M. D. Tomer* and M. R. Burkart

National Soil Tilth Laboratory, USDA Agricultural Research Service, 2150 Pammel Drive, Ames, IA 50011



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Fig. 1. Maps of Watersheds 1 and 2 of the Deep Loess Research Station (DLRS), showing topography (left) and cropping boundaries (right). Topographic contours (left map) are at a 5-m interval and labeled as meters above sea level. Locations of piezometer nests and weirs are shown in both maps; the right map also identifies the nests and shows piezometer transect locations. Table 1 names the piezometer transects and gives depths of the installations at each piezometer nest.

 


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Fig. 2. Cross-sections of hydraulic heads (given as meters of elevation) along the three transects (W2, W1, and W1rip), interpolated from June 2001 water level measurements. Contour intervals are 0.5 m of head in the left and center cross-sections, and 0.25 m of head in the right cross-section. The identifier for each piezometer nest is indicated along the land surface. Stratigraphic contacts between major deposits (till, loess, and alluvium) are indicated by thick dotted lines. Refer to Fig. 1 and Table 2 for piezometer-nest and cross-section locations and identifiers.

 


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Fig. 3. Expected residual tritium activities in 2001 for water originating as local annual precipitation between 1953 and 2001. Isotopic decay based on a 12.43-yr half-life was applied to a constructed tritium record to obtain this plot. The constructed record included local data (from Lincoln, NE; Ames, IA; and on-site), a trend in the local data, and estimates for missing years based on records from St. Louis, MO and Ottawa, ON, Canada, as specified in Table 3. Precipitation data are from International Atomic Energy Agency (1992), International Atomic Energy Agency and World Meteorological Organization (2001), and Simpkins (1995).

 


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Fig. 4. Cross-sections showing variations in ground water tritium activity (TU) along three transects (W2, W1, and W1rip) during June 2001. Tritium contours are interpreted as pre-1953 in age for waters with tritium activity of <3 TU, whereas values of >12 TU show an influence of "bomb-peak" precipitation between 1963 and 1980. Intermediate values indicate recent or mixed-age waters. Piezometers not sampled for tritium are indicated by a crossed symbol. Piezometer-nest identifiers are shown along the land surface. Refer to Fig. 1 and Table 2 for piezometer-nest and cross-section locations and identifiers.

 


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Fig. 5. Plot of stable isotope data ({delta}18O{per thousand} versus {delta}2H{per thousand}) from 33 water samples collected in Watersheds 1 and 2. A local meteoric water line (LMWL) fit to the data (solid line) has an r2 of 0.72. The global meteoric water line (GMWL; dotted line) is also plotted as a reference.

 


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Fig. 6. Cross-sections showing variations in relative isotopic enrichment or depletion, using a combined scale of {delta}18O{per thousand} and {delta}2H{per thousand}, in ground water along three transects (W2, W1, W1rip) in Watersheds 1 and 2. Piezometers not sampled for stable isotopes are indicated by a crossed symbol. Piezometer-nest identifiers are shown along the land surface. Refer to Fig. 1 and Table 2 for piezometer-nest and cross-section locations and identifiers.

 


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Fig. 7. (A) Nitrate N concentrations with depth in soils and deep sediments at Position 1D (Fig. 1), from core samples taken in 1996. (B) Depths of maximum NO3–N concentrations measured in 1972, 1974–1976, 1978, 1984 (Alberts and Spomer, 1985; Schuman et al., 1975), and 1996, plotted against cumulative baseflow from Watershed 1 since 1969.

 


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Fig. 8. Cross-sections showing variations in NO3–N concentrations in water from piezometers and deep lysimeters along three transects (W2, W1, W1rip) as measured in June 2001. Lysimeters are indicated by filled circles located above the water table, whereas piezometers are located below the water table. Installations not sampled for nitrate are indicated by a crossed symbol. Piezometer-nest identifiers are shown along the land surface. Refer to Fig. 1 and Table 2 for piezometer-nest and cross-section locations and identifiers.

 


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Fig. 9. Temporal changes in NO3–N concentrations in water collected from lysimeters and piezometers at D, S, T, and R positions in Watersheds 1 and 2 (see Fig. 1). Open symbols denote suction-cup lysimeters, black-filled symbols denote piezometers in loess, and gray-filled symbols denote piezometers near the till contact. Depths of monitoring (meters below surface) are noted above each plot. Nondetectable concentrations (<1 mg L-1) are plotted at zero. Symbols overlap in some plots. Some installations did not yield water samples every month (see Table 2).

 


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Fig. 10. Nitrate N concentrations in baseflow collected at the outlet weirs of Watersheds 1 and 2.

 





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