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Determination of Redox-Sensitive Phosphorus in Field Runoff without Sediment Preconcentration

Risto Uusitalo* and Eila Turtola

MTT Agrifood Research Finland, FIN-31600 Jokioinen, Finland



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Fig. 1. Changes in Eh, pH, total dissolved phosphorus (TDP), and soluble Fe in five runoff samples from two fine-textured soils (Sj, Sjökulla; Jo, Jokioinen) as a function of time after addition of bicarbonate and dithionite (BD); time-zero subsample is the original sample without BD addition.

 


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Fig. 2. Particulate phosphorus solubilized in chemical reduction (BD-PP) as a function of the concentration of particulate phosphorus (PP) in runoff from the Jokioinen field, n = 79.

 


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Fig. 3. Concentration of phosphorus determined after bicarbonate–dithionite extraction, filtration, and digestion of the filtrate (BD-Pt) as related to total phosphorus (TP) concentration in the 10 runoff samples studied; mean of 5 replications; the error bars represent 95% confidence intervals. The line represents the BD-Pt concentration as predicted from the equation in Fig. 2 (redox-sensitive particulate phosphorus [BD-PP] was calculated from the particulate phosphorus concentration and added to the measured total dissolved phosphorus [TDP] to give BD-Pt).

 





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