Microbial Reduction of Hexavalent Chromium under Vadose Zone Conditions
Douglas S. Olivera,
Fred J. Brockmanb,
Robert S. Bowmana and
Thomas L. Kieft*,c
a Dep. of Earth and Environ. Sci., New Mexico Inst. of Mining and Technology, Socorro, NM 87801 (D.S. Oliver, current address: MWH, 10619 South Jordan Gateway, Salt Lake City, UT 84095)
b Pacific Northwest National Lab., Richland, WA 99352
c Dep. of Biology, New Mexico Inst. of Mining and Technology, Socorro, NM 87801

View larger version (36K):
[in a new window]
|
Fig. 1. Gravimetric water contents of columns through time. Chromium(VI) and nutrients were added to the influent on Day 0. Data for Columns C2 and B2 were omitted for reasons described in text.
|
|

View larger version (22K):
[in a new window]
|
Fig. 2. Normalized tritium breakthrough curves for Column NC2 for the two tracer tests before and after 38 d of Cr(VI) and nutrient addition. The curves shown were generated with CXTFIT2 (Toride et al., 1995) for a slug width of 1 pore volume, using parameters estimated from the actual tritium tracer data (Table 4).
|
|

View larger version (32K):
[in a new window]
|
Fig. 3. Normalized Cr concentrations in the column effluents. Influent Cr concentrations were approximately 65 mg L-1. Full breakthrough of Cr would be expected after 5 d if no Cr loss mechanisms were operative.
|
|

View larger version (25K):
[in a new window]
|
Fig. 4. Cumulative Cr immobilized in the columns.
|
|
Copyright © 2003 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.