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Metal Immobilization in Soils Using Synthetic Zeolites

Leonard A. Oste{dagger}, Theo M. Lexmond and Willem H. Van Riemsdijk*

Department of Environmental Sciences, Wageningen Univ., P.O. Box 8005, 6700 EC Wageningen, the Netherlands



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Fig. 1. Aluminum released by adding HNO3 to a zeolite suspension.

 


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Fig. 2. Adsorption of Zn (a) and Cd (b) on zeolite A(PQ) at three pH levels.

 


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Fig. 3. Dissolved organic carbon (DOC) (a), Ca (b), and Zn (c) measured in solution in suspensions containing soil K1 and different additives. {diamond}, NaOH; {square}, Ca(OH)2; {circ}, cyclonic ashes; {triangleup}, zeolite A.

 


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Fig. 4. Measured (symbols) and calculated (lines) dissolved organic carbon (DOC) concentrations in suspensions containing soil K1 and different additives. {diamond}, NaOH; {square}, Ca(OH)2; {circ}, cyclonic ashes; {triangleup}, zeolite A.

 


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Fig. 5. (a) pH measured in the leachate of the first column experiment; (bf) cumulative amounts of dissolved organic carbon (DOC), Na, Ca, Zn, and Cd leached from the columns. {diamond}, no additives; {square}, 0.3% Ca(OH)2; {triangleup}, 0.5% zeolite A; {circ}, 2.5% zeolite A.

 


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Fig. 6. Free ionic concentrations of (a) Ca, (b) Zn, and (c) Cd based upon speciation calculations in the column leachates. {diamond}, no additives; {square}, 0.3% Ca(OH)2; {triangleup}, 0.5% zeolite A; {circ}, 2.5% zeolite A.

 


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Fig. 7. (a) pH measured in the leachate of the second column experiment; (bf) cumulative amounts of dissolved organic carbon (DOC), Na, Ca, Zn, and Cd leached from the columns. {diamond}, no additives; {square}, 0.1% Ca(OH)2; +, 0.5% Ca-treated zeolite A; x, 0.5% H-treated zeolite A; –, 0.5% Ca–H-treated zeolite A.

 


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Fig. 8. Free ionic concentrations of (a) Ca, (b) Zn, and (c) Cd based upon speciation calculations in the column leachates. {diamond}, no additives; {square}, 0.1% Ca(OH)2; +, 0.5% Ca-treated zeolite A; x, 0.5% H-treated zeolite A; –, 0.5% Ca–H-treated zeolite A.

 





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