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Predicted 1,3-Dichloropropene Air Concentrations Resulting from Tree and Vine Applications in California

S. A. Cryer* and I. J. van Wesenbeeck

Dow AgroSciences, 9330 Zionsville Road, Indianapolis, IN 46268



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Fig. 1. Example of the use of a Gaussian plume model to simulate air concentrations resulting from agriculturally treated fields (area source terms) within a township.

 


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Fig. 2. Cumulative distributions for field size for representative Fresno County tree and vine (T&V) applications.

 


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Fig. 3. Location of randomly distributed source terms in the township of interest for the 20-yr simulation.

 


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Fig. 4. Historical tree and vine (T&V) timings for 1,3-dichloropropene applications.

 


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Fig. 5. Experimentally measured soil flux rates for 1,3-dichloropropene (25% release) for an application rate of 132 kg/ha (active ingredient) and an injection depth between 30.5 and 45.7 cm (12 and 18 in).

 


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Fig. 6. Location of source terms for the simulation domain (single year) having two-township buffers on all sides of the centrally located township of interest.

 


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Fig. 7. Effect of neighboring township sources on 24-h maximum and annual receptor concentrations (C/Cmax-acute [five township] = 447.5 µg/m3).

 


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Fig. 8. Enlargement of Fig. 7 illustrating upper percentiles arising from the effect of neighboring township sources on 24-h maximum and annual receptor concentrations (C/Cmax-acute [five township] = 447.5 µg/m3).

 


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Fig. 9. Overlay of source terms with 24-h maximum and annual receptor concentrations for the single-year simulation (one-township border on each side).

 


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Fig. 10. Location of the top 1000 township receptors for both 24-h maximum and annual average air concentrations of 1,3-D for 1 yr in the tree and vine (T&V) rotation cycle.

 


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Fig. 11. Cumulative distribution for 24-h maximum 1,3-dichloropropene air concentrations for the entire 20-yr simulation interval and the 20-yr annual average.

 


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Fig. 12. Acute 24-h maximum concentrations surrounding each treated field 3 d following an application for the largest field (30.2 ha) in the simulation.

 





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