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Sources of Salinity Near a Coal Mine Spoil Pile, North-Central Colorado

Robert A. Zielinski*,a, James K. Ottonb and Craig A. Johnsonc

a U.S. Geological Survey, Mail Stop 973, Denver Federal Center, Denver, CO 80225
b USGS, Mail Stop 939, Denver Federal Center, Denver, CO 80225
c USGS, Mail Stop 963, Denver Federal Center, Denver, CO 80225



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Fig. 1. Location map of the study area (modified from Kirkham and Ladwig, 1980).

 


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Fig. 2. Map of the study site showing locations of water (W) and auger (A) samples.

 


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Fig. 3. Triangular plots showing the relative proportions of the major cations and anions in surface waters, mine spoil leachates, and saline soil leachates.

 


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Fig. 4. Calculated saturation indices of selected mineral phases in nine samples of surface water (W1–W9) collected at progressive distances downstream from the cattail wetland below the coal spoil pile. Positive values of saturation index (log of ion activity product/equilibrium constant) indicate oversaturation with respect to a particular phase.

 


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Fig. 5. Dissolved concentrations of selected elements in surface waters W1–W9, plotted as a function of distance downstream from the cattail wetland below the coal spoil pile.

 


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Fig. 6. Sulfur isotopic composition of total sulfur in core samples and of soluble sulfate in the spoil pile, nearby saline soil, regional soils, and surface waters W1–W9.

 


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Fig. 7. Sulfur isotopic composition plotted versus 1/SO4 for surface waters W1–W9. Dissolved sulfate increases with distance downstream. Tic marks on the apparent mixing line connecting mixing endmembers W1 and W9 indicate the calculated percentage of W9 in the mixture, based on sulfate concentrations. Estimated precision of {delta}34S values (±0.2{per thousand}) is approximated by the diameter of the dots.

 





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