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Immobilization of Cesium-137 and Uranium in Contaminated Sediments Using Soil Amendments

John C. Seaman*, T. Meehan and P.M. Bertsch

Advanced Analytical Center for Environmental Sciences, Savannah River Ecology Lab., Univ. of Georgia, Aiken, SC 29802



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Fig. 1. Effect of single reagent-grade amendments on 1.0 mol L-1 NH4Cl-extractable 137Cs+ after equilibrating for 30 d in 0.001 mol L-1 CaCl2. Error bars indicate the standard deviation of the means.

 


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Fig. 2. Effect of various single reagent-grade amendments (hydroxyapatite, illite, zeolite) on 88Sr concentration (A) and pH (B) after equilibrating for 30 d in 0.001 mol L-1 CaCl2. Figure C is the subsequent 1.0 mol L-1 NH4Cl-extractable Sr after equilibration. Error bars indicate the standard deviation of the means.

 


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Fig. 3. Effect of various single reagent-grade amendments (hydroxyapatite, illite, zeolite) on U concentration (A) and pH (B) after equilibrating for 30 d in 1.0 mM CaCl2. Figure C is the subsequent 1.0 mol L-1 NH4Cl-extractable U after equilibration. Error bars indicate the standard deviation of the means.

 


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Fig. 4. Effect of various combined amendments (hydroxyapatite [HA] + illite and HA + zeolite) on U concentration (A) and pH (B) after equilibrating for 30 d in 0.001 mol L-1 CaCl2. Figure C is the subsequent 1.0 mol L-1 NH4Cl-extractable U after equilibration. Note that the results for equilibrium (A) and extractable (B) U for the two treatments are essentially identical. Error bars indicate the standard deviation of the means.

 


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Fig. 5. Effluent 137Cs+ (A) and U (B) concentration for hydroxyapatite [HA]-amended and unamended Sediment A columns leached with 1.0 mol L-1 NH4Cl, 0.001 mol L-1 CaCl2, or 0.001 mol L-1 CaCl2 + 0.0005 mol L-1 NH4Cl. Note that the 137Cs+ levels for all but the 1.0 mol L-1 NH4Cl leachates were below detection limits (<18.6 Bq L-1) regardless of amendment treatment. Error bars indicate the standard deviation of the means.

 





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