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Removal of Uranium(VI) from Contaminated Sediments by Surfactants

Frederic Gadellea,b, Jiamin Wana and Tetsu K. Tokunagaa

a Lawrence Berkeley National Lab., MS 90-1116, 1 Cyclotron Road, Berkeley, CA 94720
b Chevron Petroleum Technology Co., 6001 Bollinger Canyon Rd., San Ramon, CA 94583



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Fig. 1. (a) Uranium sorption isotherm. (•): o = 10-7 to 10-4 M, = = 1 mM, and pH = 4 ± 0.05. K and 1/n are the Freundlich coefficients obtained using a nonlinear fit: Usorbed = K x Ul/naq. (b) Uranium sorption as a function of pH. o = 10-6 M. 1 g of soil 10 mL-1 of solution. = 1 mM and = 1 , 10 , and 100 mM

 


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Fig. 2. Uranium and iron solubilization as a function of chemical treatments. [U(VI)]o,sorbed = ca. 10-5 mol kg-1. Treatment concentrations are 60 mM. The pH of the soil solutions is indicated on the graph

 


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Fig. 3. (a) Uranium desorption as a function of the treatment concentration. [U(VI)]o,sorbed = ca. 10-5 mol kg-1. (b) Uranium desorption as a function of the amount of uranium initially sorbed. added = 10-7, 10-6, 10-5, and 10-4 M. [Treatment] = 60 mM

 


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Fig. 4. Uranium desorption as a function of the soil to liquid ratio. [U(VI)]o,sorbed = ca. 10-5, 5 x 10-6, and 2 x 10-6 mol kg-1 for 1, 2, and 5 g of soil 10 mL-1 of solution, respectively. [Treatment] = 60 mM. The pH of the soil solutions is indicated on the graph

 





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