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Published in J Environ Qual 6:421-426 (1977)
© 1977 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Chemical Monitoring of Sewage Sludge in Pennsylvania1

W. T. Doty, D. E. Baker and R. F. Shipp2

ABSTRACT

Sewage sludge samples were collected biweekly and analyzed for several components to determine the sampling procedures which should be required for the routine chemical monitoring of sewage sludge produced by a given treatment plant. While the composition varied significantly over time for every component and every plant, the standard deviation, expressed as a percentage of the mean for each treatment plant, indicated that two-thirds of the values would be within the range of the true average value plus or minus 20 to 50%.

Analyses for all samples collected in Pennsylvania, including those analyzed as a part of a service program, indicated that without chemical analysis the composition with respect to N, P, and K varied too much to establish an accurate prediction of the fertilizer value of unanalyzed sludge. In addition, the concentrations of the essential but phytotoxic elements, especially Zn and Cu, as well as trace elements harmful to the food chain, varied greatly among the treatment plants studied.

Key Words: heavy metals • sludge • chemical analysis • cadmium • zinc • copper • lead • chromium


NOTES

1 Contribution of the Pennsylvania Agric. Exp. Stn., University Park, PA 16802. Authorized for publication on 3 Nov. 1976 as Paper no. 5195 in the J. Series.

2 Research Assistant, Professor of Soil Chemistry, and Associate Professor of Agronomy Extension, respectively.

Received for publication November 15, 1976.





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Copyright © 1977 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.