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Published in J Environ Qual 5:243-246 (1976)
© 1976 American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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The Effects of Temperature and Soil Water on Conversion of DDT to DDE in Soil1

W. D. Guenzi and W. E. Beard2

ABSTRACT

A laboratory study was conducted to determine the rates of DDT (1,1,1-trichloro-2,2-bis [p-chlorophenyl] ethane) degradation and DDE (1,1-dichloro-2,2-bis [p-chlorophenyl] ethylene) formation in soil. Degradation rates increased with higher temperatures and in the presence of water. Of the DDT mixed with Raber silty clay loam, 82.1, 74.5, 53.2, and 38.3% was recovered as DDT and 6.7, 12.5, 21.6, and 34.8% as DDE after 140 days incubation at 30, 40, 50, and 60C, respectively. A comparison of DDE formation in sterile and nonsterile soil showed that 84% of the conversion was due to a chemical process at 30C and 91% at 60C. In sterile systems at 30C, rates of DDE formation were similar in submerged soil and soil at 1/3 bar suction, and both were much higher than in air-dried soil.

Key Words: pesticide • insecticide • chemical degradation • persistence • decomposition • microbial degradation


NOTES

1 Contribution from U. S. Dep. of Agric., Agric. Res. Serv., Western Region, P. O. Box E, Fort Collins, CO 80522, in cooperation with Colorado State Univ. Exp. Stn., Sci. J. Ser. No. 2049.

2 Soil Scientist and Chemist, USDA.

Received for publication June 2, 1975.





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