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TECHNICAL REPORTS

Waste Management

Chemical Fractionation of Phosphorus in Stabilized Biosolids

^a Dep. of Soil and Water Sciences, Faculty of Agricultural, Food and Environmental Quality Sciences, The Hebrew Univ. of Jerusalem, Rehovot 76-100, Israel
^b Cooperative Inst. for Marine and Atmospheric Studies, Rosenstiel School of Marine and Atmospheric Sciences, Univ. of Miami, 4600 Rickenbacker Causeway, Miami, FL 33149

^* Corresponding author (Shenker{at}agri.huji.ac.il).

Received for publication May 3, 2007. Three chemicals—ferrous sulfate (FeSul), calcium oxide (CaO), and aluminum sulfate (alum)—were applied at different rates to stabilize P in fresh, anaerobically digested biosolids (FBS) obtained from an activated sewage treatment plant. A modified Hedley fractionation procedure was used to assess P forms in these sludge-borne materials and in a biosolids compost (BSC) prepared from the same FBS. Each biosolids material exhibited a unique pattern of P distribution among fractions. The most available P forms, namely: (i) water-soluble P (WSP); (ii) membrane-P; and (iii) NaHCO₃–P, were stabilized by small rates of each of the chemicals; but the P transformation into more stable forms depended on the type of chemical added. The stabilized P forms were enhanced by high rates of CaO and FeSul, but were reduced by high rates of alum. The organic P (P_o) in the first three fractions of the FeSul- and alum-stabilized biosolids was enhanced by the chemical addition, and P_o transformation from NaOH-P_o into NaHCO₃–P_o was found in calcium-stabilized biosolids. A positive relationship was found between NaHCO₃–P_o and the NaHCO₃–extracted organic C in all chemically stabilized biosolids. One-step extraction by NaHCO₃ or NaOH underestimated P extraction compared to the stepwise extraction. The reported results are consistent with solid-state P speciation reported earlier and contribute important information for optimizing biosolids stabilization to reduce P loss after incorporation in soils and for maximizing soil capacity to safely store pre-stabilized biosolids.

Abbreviations: alum, Al-sulfate • BSC, biosolids compost • C_o, organic carbon • FeSul, ferrous sulfate • FBS, fresh dewatered anaerobically digested biosolids • P_i, inorganic phosphorus • P_o, organic phosphorus • WSP, water-soluble P