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TECHNICAL REPORTS

Heavy Metals in the Environment

Distribution of Copper, Zinc, and Phosphorus in Coastal Plain Soils Receiving Repeated Liquid Biosolids Applications

Virginia Tech Univ., Blacksburg, VA 24061

^* Corresponding author (bsukkari{at}vt.edu).

Received for publication December 22, 2006. Continuous N-based application of biosolids contributes to a gradual increase of trace elements and P in soils. The objectives of this study were to assess the accumulation and vertical transport of Cu, Zn, C, N, and P within the profile of two coastal plain soils. Liquid (6–8% total solids) biosolids were applied to an Acredale silt loam (fine silty, mixed, thermic typic Ochraqualfs) and Bojac loamy sand (coarse loamy, mixed, thermic typic Hapludult) annually from 1984 to 1998. The repeated applications supplied 70, 204, and 3823 kg ha^–1 of Cu, Zn, and P, respectively, to the Acredale and 81, 225, and 4265 kg ha^–1 of Cu, Zn, and P, respectively, to the Bojac. The total C and N contents were not different than background levels in the Bojac soil and were slightly higher in the Acredale soil 7 years after cessation of biosolids application. Phosphorus, Cu and Zn are still concentrated in the top 0.25 m of the Acredale soil. Enrichment of P, Cu, and Zn were detected to the deepest soil increment in the coarse-textured Bojac soil. Approximately 20 to 40% of the Cu and Zn applied in the biosolids could not be accounted, which was likely due to a combination of leaching and incomplete extraction. Excessive Mehlich 1-P concentrations and a high degree of P saturation were found in amended soil, raising the potential for P release to runoff or leaching water.